Self-consistent modelling of non-linear effective properties of polycrystalline ferroelectric ceramics

A constitutive model for the non-linear effective behaviour of ferroelectric ceramics is presented. The model is developed on the basis of the effective medium approximation (EMA), which describes the interaction of the crystallites in a statistical way. Additionally, a particular simplified domain configuration within the crystallites and the possibility of domain wall motion are taken into account. In connection with a thermodynamic criterion for the domain wall displacement the volume fractions of the domains can be calculated dependent on the crystallite orientation and the applied load in a self-consistent manner. This mechanism leads to an extrinsic contribution to the effective behaviour. If the domain wall displacement is associated with energy dissipation the macroscopic behaviour is non-linear and hysteretic.