Visualization of aerosol particles generated by near infrared nano- and femtosecond laser ablation

The expansion of aerosols generated by near infrared (NIR) nanosecond (ns) and femtosecond (fs) laser ablation (LA) of metals at atmospheric pressures was explored by laser-induced scattering. In order to achieve adequate temporal and spatial resolution a pulsed laser source was utilized for illuminating a 0.5 mm-wide cross section of the expanding aerosol. It could, for instance, be shown that NIR-ns-LA under quiescent argon atmosphere provokes the formation of a dense aerosol confined within a radially propagating vortex ring. The expansion dynamics achieved under these conditions were found to be fairly slow whereas the degree of aerosol dispersion for NIR-ns-LA using helium drastically increased due to its lower viscosity. As a consequence, the maximum diameter of expansion differed by a factor of approximately four. The trajectories of aerosol particles generated by NIR-ns-LA using argon could, furthermore, be simulated on the basis of computational fluid dynamics (CFD). For this purpose, a model inspired by the thermal character of NIR-ns-LA taking into account a sudden temperature build-up of 10,000 K at the position of the laser focus was implemented. trast, NIR-fs-LA generally resulted in extremely dynamic expansion patterns. Initial aerosol velocities derived from corresponding expansion plots varied from 10 m/s up to 30 m/s for fs-LA using argon and helium, respectively. Our results, moreover, indicate that fs-LA carried out under helium atmosphere favours a chaotic aerosol expansion. Analytical implications concerning, e.g. dispersion phenomena or the choice of the LA protocol and physical dimensions of future ablation cell designs are discussed.