• Title of article

    Effect of Pd on the interaction of formic acid with TiO2(110)

  • Author/Authors

    Chang، نويسنده , , Z. and Thornton، نويسنده , , G.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    7
  • From page
    303
  • To page
    309
  • Abstract
    The effect of coadsorbed Pd on the adsorption of HCOOH on TiO2(110) at room temperature has been investigated using HREELS. At Pd coverages below 12 ML, formate is evidenced that is probably bonded to Ti sites on bare areas of the substrate. Additional CO species are identified corresponding to CO bound to Pd clusters as well as HCO and/or CO bound to sites at the perimeter of the clusters. There is evidence of Pd encapsulation by TiO2−x after annealing the Pd overlayer to 800 K.
  • Keywords
    Titanium oxide , Vibrations of adsorbed molecules , Carboxylic acid , Chemisorption , Electron energy loss spectroscopy (EELS) , GROWTH , Low index single crystal surfaces , PALLADIUM
  • Journal title
    Surface Science
  • Serial Year
    2000
  • Journal title
    Surface Science
  • Record number

    1688750