Title of article :
Surface chemistry of alkyl and perfluoro ethers: a Fourier transform infrared study of adsorption and decomposition of CF3OCF2OCF3 on Al2O3 surface
Author/Authors :
Li، نويسنده , , Ping and Ng، نويسنده , , L.M. and Liang، نويسنده , , Jim، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Abstract :
The interaction of CF3OCF2OCF3 on Al2O3 surface was investigated by Fourier transform infrared (FTIR) under both ‘vacuum’ and ‘pressure’ conditions. It was found that CF3OCF2OCF3 decomposed only under ‘pressure’ conditions. Fluoroformate FCOO (ads) was formed and stayed adsorbed on the surface up to 550 K. The reactivities of CF3OCF2OCF3 and CF3OCF3 on Al2O3 surface are compared and the reaction mechanisms are also discussed.
Keywords :
Infrared absorption spectroscopy , Surface chemical reaction , Aluminium oxide , ethers , Polycrystalline surfaces , Catalysis
Journal title :
Surface Science
Journal title :
Surface Science
