Title of article :
Liquid–liquid equilibria for ternary systems of dimethyl carbonate + C1–C4 alcohols + water at 298.15 K and atmospheric pressure
Author/Authors :
Hwang، نويسنده , , In-Chan and Park، نويسنده , , So-Jin and Han، نويسنده , , Kyu-Jin and In، نويسنده , , Se-Jin، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Pages :
5
From page :
499
To page :
503
Abstract :
The ternary liquid–liquid equilibria (LLE) of the following systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {dimethyl carbonate (DMC) + methanol + water}, {DMC + ethanol + water}, {DMC + 1-propanol + water}, {DMC + 2-propanol + water}, {DMC + 1-butanol + water} and {DMC + 2-butanol + water}. The experimental ternary LLE data were correlated with the non-random two liquid (NRTL) and UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. In addition, the Bachman–Brown correlation was used to ascertain the reliability of the experimental data for each system.
Keywords :
water , Correlation , Liquid–liquid equilibria , Dimethyl carbonate , alcohols
Journal title :
Journal of Industrial and Engineering Chemistry
Serial Year :
2012
Journal title :
Journal of Industrial and Engineering Chemistry
Record number :
1709820
Link To Document :
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