Title of article :
Electrochemical properties of the solid polymer electrolyte PEO20–LiSO3CF3–Urea1.5
Author/Authors :
Zhang، نويسنده , , Ding-Xiang Yan، نويسنده , , Hui and Zhang، نويسنده , , Huan and Zhu، نويسنده , , Zhi and Qilu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2011
Abstract :
In this work, a new type of solid polymer electrolyte, formulated as PEO20–LiSO3CF3–Ureax, is prepared by solution-casting technique. Among the different urea-containing samples, PEO20–LiTf–Urea1.5 presents an optimum ambient temperature ionic conductivity of 5.1 × 10− 6 S/cm, enhanced by nearly 100 times over the PEO20-LiTf system. The mechanism for the increase in conductivity is discussed by the joint analysis of DSC and ATR-IR measurements. Urea molecules coordinate with lithium ions via carbonyl groups, which efficiently decrease the concentration of triple cations [Li2Tf]+. The addition of urea results in augmented cation transference and increased interface impedance. Analysis of the salt diffusion coefficient confirms that urea enhances the transport of lithium salts. The prepared SPE is tested by galvanostatic charge-discharge cycling in lithium secondary cells. Data obtained for PEO20–LiSO3CF3–Urea1.5 reveals that the upper voltage limit in the LiCoO2-based cells should be about 4.0 V versus Li/Li+.
Keywords :
Solid polymer electrolyte , urea , Solution-casting technique , Polymer ethylene oxide
Journal title :
Solid State Ionics
Journal title :
Solid State Ionics