Title of article
Effect of molecular weight on conductivity of polymer electrolytes
Author/Authors
Teran، نويسنده , , Alexander A. and Tang، نويسنده , , Maureen H. and Mullin، نويسنده , , Scott A. and Balsara، نويسنده , , Nitash P. Balsara، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
4
From page
18
To page
21
Abstract
The ionic conductivity, σ, of mixtures of poly(ethylene oxide) (PEO) and lithium bis(trifluoromethanesulfone)imide (LiTFSI) was measured as a function of molecular weight of the PEO chains, M, over the range 0.2–5000 kg/mol. Our data are consistent with an expression σ = σ0 + K/M proposed by Shi and Vincent [Solid State Ionics 60 (1993)] where σ0 and K are exponential and linear functions of inverse temperature respectively. Explicit expressions for σ0 and K are provided.
Keywords
Molecular weight dependence , Polymer electrolyte , ionic conductivity
Journal title
Solid State Ionics
Serial Year
2011
Journal title
Solid State Ionics
Record number
1711096
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