Title of article :
YSZ-carbonate dual-phase membranes for high temperature carbon dioxide separation
Author/Authors :
Ahn، نويسنده , , Howon and Kim، نويسنده , , Daeho and Melgar، نويسنده , , Vيctor Manuel Aceituno and Kim، نويسنده , , Jinsoo and Othman، نويسنده , , Mohd Roslee and Nguyen، نويسنده , , Hoang Viet Phuc and Han، نويسنده , , Jonghee and Yoon، نويسنده , , Sung Pil، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Pages :
6
From page :
3703
To page :
3708
Abstract :
A dense yttria stabilized zirconia (YSZ)-carbonate membrane that was impermeable to gas at low temperature became highly permeable to CO2 at temperature above the melting point of the carbonate. The CO2 permeance across the YSZ-molten carbonate dual-phase membrane was observed to be higher than 0.1 × 10−8 mol/m2/Pa/s at temperature >650 °C. The movement of ions was promoted at high temperature as YSZ and molten carbonate became highly conductive to oxygen ions and carbonate species, respectively. Addition of poly(methyl methacrylate) (PMMA) during preparation of macroporous YSZ support created interconnected pore structures that were found conducive for carbonate infiltration and integration with the membrane materials.
Keywords :
Molten carbonate , Carbon dioxide , Permeability , MEMBRANE , YSZ
Journal title :
Journal of Industrial and Engineering Chemistry
Serial Year :
2014
Journal title :
Journal of Industrial and Engineering Chemistry
Record number :
1712312
Link To Document :
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