Author/Authors :
Da Cunha، نويسنده , , L and Ilundain، نويسنده , , P and Salazar، نويسنده , , R and Alvarez، نويسنده , , D and Barandiaran، نويسنده , , M.J and Asua، نويسنده , , J.M، نويسنده ,
Abstract :
The formation of volatile organic compounds through secondary reactions during the post-polymerization of vinyl acetate containing latexes using organic hydroperoxides with ascorbic acid as redox initiator was investigated. It was found that such initiator systems are highly effective in reducing free vinyl acetate but organic by-products are produced. A reaction scheme consistent with the kinetic data is presented.
