Title of article :
Enantioselective acetylation of racemic alcohols by Manihot esculenta and Passiflora edulis preparations
Author/Authors :
Machado، نويسنده , , Luciana L. and de Gonzalo، نويسنده , , Gonzalo and Lemos، نويسنده , , Telma L.G. and de Mattos، نويسنده , , Marcos Carlos and de Oliveira، نويسنده , , Maria da Conceiçمo F. and Gotor-Fernلndez، نويسنده , , Vicente and Gotor، نويسنده , , Vicente، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Immobilized Manihot esculenta and Passiflora edulis juice preparations have been employed as stereoselective biocatalysts in the enzymatic acetylation of a set of racemic alcohols. Depending on the reaction conditions and the substrate structure, good to excellent enantioselectivities can be achieved in the preparation of the (S)-alcohols and (R)-esters, compounds presenting high interest in organic synthesis.
Keywords :
Chiral esters , Biocatalysis , Enzymatic acylation , Immobilization protocols
Journal title :
Journal of Molecular Catalysis B Enzymatic
Journal title :
Journal of Molecular Catalysis B Enzymatic