Title of article
Stereoselective esterification of 2,6-dimethyl-1,7-heptanedioic acid, catalysed by Candida rugosa lipase
Author/Authors
Hedenstrِm، نويسنده , , Erik and Edlund، نويسنده , , Helen and Lund، نويسنده , , Susan، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
7
From page
53
To page
59
Abstract
The immobilised Candida rugosa lipase (CRL) displayed S-preference for both stereogenic centres in this sequential esterification of 2,6-dimethyl-1,7-heptanedioic acid (1) (pure meso and meso: (±) mixture, 53/47) with n-butanol in cyclohexane at aw=0.8. The reaction was faster when short-chain primary n-alcohols was used and very slow, or even none reactive, when a long-chain alcohol was used.
Keywords
Candida rugosa , Synthesis , Esterification , 2 , stereoselective , 6-dimethyl-1 , 7-heptanedioic acid
Journal title
Journal of Molecular Catalysis B Enzymatic
Serial Year
2003
Journal title
Journal of Molecular Catalysis B Enzymatic
Record number
1716218
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