Title of article :
Synthesis of fluorocarbon-modified poly(acrylic acid) in supercritical carbon dioxide
Author/Authors :
Hu، نويسنده , , Hongqi and He، نويسنده , , Song-Tao and Feng، نويسنده , , Jiachun and Chen، نويسنده , , Mingcai and Cheng، نويسنده , , Rongshi، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2002
Abstract :
Copolymerization of acrylic acid and 1H,1H,11H-perfluoroundecyl acrylate in supercritical carbon dioxide was successfully carried out. The products were obtained in the form of dry white powder with diameter about 0.2 μm. Viscosities of 2% aqueous solution of the copolymers were much higher than that of poly(acrylic acid) and it showed a strong dependence on pH, which is due to the intermolecular association.
Keywords :
Fluorocarbon-modified poly(acrylic acid) , Hydrophobically association , Supercritical carbon dioxide
