Dynamic mechanical and melt rheological properties of sulfonated poly(butylene succinate) ionomers

A series of poly(butylene succinate) ionomers (PBSi) containing 5-sodium sulfoisophthalate units were prepared by bulk polymerization of succinic acid and 1,4-butanediol in the presence of dimethyl 5-sulfoisophthalate sodium salt (DMSI) up to 5 mol% of diacid monomer. Conspicuous variation of the storage modulus for PBSi was observed, depending on the content of DMSI. The increasing rate of cluster Tg was lower compared to those of amorphous polymer-based ionomers. These results were probably due to the lower clustering ability of semi-crystalline PBSi as compared with amorphous-based ionomers. Non-contact atomic force microscopy confirmed that the size of PBSi-3 clusters was about 40∼50 nm, demonstrating that the clusters were aggregated. Melt rheological analysis was carried out to investigate the effects of ionic groups on the rheological properties as a function of temperature or shear force in the molten state. The melt viscosities of PBSi showed higher values than the parent PBS up to about 190 °C, while with further increasing temperature a falling inflection region of melt viscosity was observed. It was suggested that the relaxation of PBSi chains was due to the thermal dissociation of ionic aggregates.