Title of article :
In situ 1H NMR studies of free radical cryopolymerization
Author/Authors :
Kirsebom، نويسنده , , Harald and Rata، نويسنده , , Gabriel and Topgaard، نويسنده , , Daniel and Mattiasson، نويسنده , , Bo and Galaev، نويسنده , , Igor Yu.، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2008
Pages :
4
From page :
3855
To page :
3858
Abstract :
Free radical polymerization of DMAAm (dimethylacrylamide)-co-PEG diacrylate in a semi-frozen aqueous solution was studied using 1H NMR, which enables to monitor the non-frozen water as well as the reaction of monomers over time. It was possible to confirm the presence of a heterogeneous system with a liquid phase where the monomers were concentrated and the reaction proceeded. The resulting macroporous polymeric structure with dense pore walls was confirmed using scanning electron microscopy (SEM).
Keywords :
In situ NMR study , Cryopolymerization , Semi-frozen state
Journal title :
Polymer
Serial Year :
2008
Journal title :
Polymer
Record number :
1731954
Link To Document :
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