Author/Authors :
Kirsebom، نويسنده , , Harald and Rata، نويسنده , , Gabriel and Topgaard، نويسنده , , Daniel and Mattiasson، نويسنده , , Bo and Galaev، نويسنده , , Igor Yu.، نويسنده ,
Abstract :
Free radical polymerization of DMAAm (dimethylacrylamide)-co-PEG diacrylate in a semi-frozen aqueous solution was studied using 1H NMR, which enables to monitor the non-frozen water as well as the reaction of monomers over time. It was possible to confirm the presence of a heterogeneous system with a liquid phase where the monomers were concentrated and the reaction proceeded. The resulting macroporous polymeric structure with dense pore walls was confirmed using scanning electron microscopy (SEM).