Multivariate analysis of 13C NMR spectra of methacrylate copolymers and homopolymer blends

13C NMR spectra of copolymers of methyl methacrylate and tert-butyl methacrylate with various chemical compositions, the homopolymers of the two methacrylates, and blends of the homopolymers with various blend ratios were subjected to principal component analysis. The first and second principal components correlated chemical composition and the randomness of comonomer sequence, respectively. Chemical composition of the copolymers was determined with high accuracy and precision by the partial least-squares regression without assignment of individual resonance peaks.