Author/Authors :
Bauhofer، نويسنده , , W. and Schulz، نويسنده , , S.C. and Eken، نويسنده , , A.E. and Skipa، نويسنده , , T. and Lellinger، نويسنده , , D. and Alig، نويسنده , , I. and Tozzi، نويسنده , , E.J. and Klingenberg، نويسنده , , D.J.، نويسنده ,
Abstract :
Controlling the electrical conductivity is a critical issue when processing material systems consisting of an insulating matrix filled with conductive particles. We provide experimental evidence that given shear rates result in specific conductivity levels in such different systems as high-viscosity carbon nanotube/polymer melt or low-viscosity carbon nanotube/epoxy fiber suspensions. The steady-state conductivities are independent of the initial state of the dispersion. The observed behavior is modeled phenomenologically by the competition between build-up and destruction of conductive filler network. A particle-level simulation of flowing fiber suspension also reflects the observed behavior. Our results show that properties of particulate suspensions can be controlled by steady shear. They should be considered to obtain reproducible properties in shear-based processing technologies as injection molding or resin transfer molding.
