Title of article
Structural chirality of cholesteric liquid crystal produces atropisomerism: Chiroptical polyisocyanides from achiral monomer in cholesteric liquid crystal matrix
Author/Authors
Goto، نويسنده , , Hiromasa and Ohkawa، نويسنده , , Satoshi and Ohta، نويسنده , , Reina، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2011
Pages
6
From page
1932
To page
1937
Abstract
1-Naphthyl isocyanide was polymerized with Ni(II) catalyst in a cholesteric matrix at the liquid crystal (LC) temperature range. The resultant polymers showed optical activity. In this reaction, the structural chirality of cholesteric LC effectively functions to impart one-handed helicity on the corresponding polymers as an optically active atropisomer.
Keywords
Helical , isocyanide , cholesteric liquid crystal
Journal title
Polymer
Serial Year
2011
Journal title
Polymer
Record number
1737319
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