• Title of article

    An anionic weak acceptor 2-aminomethylsulfo-3,5,6-trichloro-1, 4-benzoquinone and its BEDT-TTF-based charge-transfer salts

  • Author/Authors

    Akutsu، نويسنده , , Hiroki and Yamada، نويسنده , , Jun-ichi and Nakatsuji، نويسنده , , Shin’ichi and Turner، نويسنده , , Scott S.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2007
  • Pages
    4
  • From page
    144
  • To page
    147
  • Abstract
    We have prepared a novel organic anionic weak acceptor, 2-aminomethylsulfo-3,5,6-trichloro-1,4-benzoquinone (1), as a PPh4 salt. Cyclic voltammetry indicates that its reduction potential is 0.53 V lower than that of chloranil. Electrocrystallisation with BEDT-TTF gave two salts, β - β -(BEDT-TTF)2(1)⋅0.5H2O (2) and β ″ - (BEDT-TTF)2(1)⋅CH3OH (3). Their crystal structures and physical properties are reported.
  • Keywords
    A. Organic crystals
  • Journal title
    Solid State Communications
  • Serial Year
    2007
  • Journal title
    Solid State Communications
  • Record number

    1763935