• Title of article

    Eigenvalue problem formulation of coupled-cluster expansions through intermediate Hamiltonians

  • Author/Authors

    Nebot-Gil، نويسنده , , I and Sanchez-Marin، نويسنده , , J and Heully، نويسنده , , J.L. and Malrieu، نويسنده , , J.P and Maynau، نويسنده , , D، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1995
  • Pages
    5
  • From page
    45
  • To page
    49
  • Abstract
    Using the intermediate Hamiltonian formalism, it is shown that coupled-cluster doubles (CCD) or singles and doubles (CCSD) may be formulated as an eigenvalue problem by dressing properly the doubles or singles and doubles configuration interaction matrix. The dressing may be either diagonal or non-diagonal. The so-formulated CC method converges even in nearly degenerate situations where the traditional set of coupled equations faces usually divergent behaviour.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1995
  • Journal title
    Chemical Physics Letters
  • Record number

    1772783