Author/Authors :
Zalyubovsky، نويسنده , , Sergey J. and Wang، نويسنده , , Dongbing and Miller، نويسنده , , Terry A.، نويسنده ,
Abstract :
The first observation of a sharp, structured electronic spectrum for a fluorinated alkyl peroxy radical is reported using the technique of cavity ringdown spectroscopy (CRDS). The T00 value for the Ã2A′−X̃2A″ transition of CF3O2 has been determined to be 6656(3) cm−1; values for à state vibrational frequencies have also been determined. Initial kinetic observations on CF3O2 have been carried out, using CRDS to monitor its concentration.
