Zinc-67 nuclear magnetic resonance spectroscopy of solids

Solid-state 67Zn nuclear magnetic resonance (NMR) spectra have been reported for ZnO, ZnS, ZnSO4·7H2O and Zn(CH3COO)2. From the 67Zn NMR spectra obtained for stationary and magic-angle spinning (MAS) powder samples, useful parameters of chemical shift anisotropy (CSA) and nuclear quadrupole coupling constant (NQCC) are determined. The results demonstrate the feasibility of natural abundance 67Zn NMR studies on solids.