Author/Authors :
David Lee and Wai Ming Kwok، نويسنده , , Wai Kit Ma، نويسنده , , Chensheng and Phillips، نويسنده , , David and Parker، نويسنده , , Anthony W and Towrie، نويسنده , , Michael and Matousek، نويسنده , , Pavel and Lee Phillips، نويسنده , , David، نويسنده ,
Abstract :
We present picosecond time-resolved resonance Raman spectra that demonstrate formation of the iso-CH2Br–I species following A-band excitation of bromoiodomethane in cyclohexane solvent at room temperature. The iso-CH2Br–I species is produced within several ps and appears to decay with a half-life on the 2–3 ns time scale. We compare these results to previous studies on solution phase photodissociation of dihalomethanes.
