Author/Authors :
Sa?ek، نويسنده , , P. and Carravetta، نويسنده , , V. and Gelʹmukhanov، نويسنده , , F.Kh. and ?gren، نويسنده , , H. and Schimmelpfennig، نويسنده , , B. and Piancastelli، نويسنده , , M.-N. and Sorensen، نويسنده , , L. and Feifel، نويسنده , , R. and Hjelte، نويسنده , , I. and B?ssler، نويسنده , , Stephanie M. and Svensson، نويسنده , , S. and Bj?rneholm، نويسنده , , O. and Naves de Brito، نويسنده , , A.، نويسنده ,
Abstract :
Resonant excitation to the F1s-σ* dissociative state in hydrogen fluoride gives a photoelectron spectrum where the spectator part contains strong atomic lines but a participator part where such lines are lacking. We demonstrate that this contrasting behaviour between the two parts is due to a strong dynamical suppression of the resonant contribution, making direct main state photoionization the dominating channel even at resonant conditions.