Author/Authors :
Rackham، نويسنده , , Edward J. and Huarte-Larranaga، نويسنده , , Fermin and Manolopoulos، نويسنده , , David E.، نويسنده ,
Abstract :
A detailed statistical theory of atom–diatom insertion reactions is derived by combining the early statistical ideas of Pechukas and Light with the coupled-channel capture theory of Clary and Henshaw. The theory is applied to the N(2D)+H2 and O(1D)+H2 reactions and found to give results in good agreement with the exact quantum mechanical integral cross sections reported recently by Honvault and Launay.