Author/Authors :
Bouvier، نويسنده , , A.J. and Bacis، نويسنده , , R. and Bussery، نويسنده , , B. and Churassy، نويسنده , , S. and Inard، نويسنده , , D. and Nota، نويسنده , , M. and Brion، نويسنده , , J. and Malicet، نويسنده , , J. and Anderson، نويسنده , , S.M.، نويسنده ,
Abstract :
We report a high-resolution study of the Wulf bands of ozone. A preliminary analysis of the ratational structure in two vibronic bands yields the band origin T0 = 9555.49 ± 0.25 cm−1, the bending frequency ω2 = 530.9 ± 0.4 cm−1 and geometries (R, θ) for the corresponding bound vibrational levels of the upper state, which is most likely to be 3A2. Rotational levels extend to at least 1090 cm−1 above T0. The radiative lifetime is ∼ 0.1−0.01 s, indicating the stateʹs metastable character.
