Author/Authors :
Bellert، نويسنده , , D. and Buthelezi، نويسنده , , T. and Lewis، نويسنده , , V. and Dezfulian، نويسنده , , K. and Reed، نويسنده , , D. and Hayes، نويسنده , , T. and Brucat، نويسنده , , P.J.، نويسنده ,
Abstract :
Rotationally resolved photodissociation spectra of mass-selected internally cold 58Ni2+ have been observed for twenty bands in four different electronic transitions of the isolated ion. The rotational analysis provides rotational constants as well as the total angular momentum (spin + orbit) along the internuclear axis for both states in each transition. The rotation-vibration constant, αe, and the equilibrium bond length re were also determined for three electronic states. An estimate of the excited state lifetime is also presented.