Author/Authors :
Critchley، نويسنده , , Andrew D.J and King، نويسنده , , George C and Kreynin، نويسنده , , Peter and Lopes، نويسنده , , M.Cristina A and McNab، نويسنده , , Iain R and Yencha، نويسنده , , Andrew J، نويسنده ,
Abstract :
Vibrationally resolved threshold photoelectrons in coincidence (TPEsCO) spectra of the X3Σ− and a1Δ states of HCl2+ and DCl2+ are compared with ab initio simulations. The four resonances observed in the TPEsCO spectra of both the X3Σ− and a1Δ states of HCl2+ are assigned as three quasi-bound vibrational levels and one continuum resonance with an energy greater than the potential barrier maximum. The four clearly identified resonances observed in the TPEsCO spectra of both the X3Σ− and a1Δ states of DCl2+ are assigned as quasi-bound vibrational levels.
