Author/Authors :
Andrews، نويسنده , , Peter M. and Pryor، نويسنده , , Brian A. and Palmer، نويسنده , , Phillip M. and Topp، نويسنده , , Michael R.، نويسنده ,
Abstract :
Rotational coherence experiments have been carried out for 1:1 van der Waals complexes of perylene with water and methanol. The observed inertial properties are consistent with structures corresponding to potential-energy minima calculated via MM2 techniques. The results show that both types of complex involve hydrogen-bonding to π-electrons on the perimeter of the aromatic molecule.
