Author/Authors :
Qian، نويسنده , , X.-M and Song، نويسنده , , Y and Lau، نويسنده , , K.-C and Ng، نويسنده , , C.Y. and Liu، نويسنده , , Jianbo and Chen، نويسنده , , Wenwu and He، نويسنده , , G.Z، نويسنده ,
Abstract :
We have examined the titled reaction near its threshold using the pulsed field ionization photoelectron–photoion coincidence method. The measured 0 K threshold (18.220±0.002 eV) has made possible the determination of more precise values for the 0 K bond dissociation energies for D–OD+ (5.584±0.002 eV) and D–OD (5.191±0.002 eV) and the 0 K heats of formation (ΔH0f0ʹs) for OD+ (308.83±0.05 kcal/mol) and OD (8.38±0.05 kcal/mol). We found that the available energetic data for the OD/OD+ and D2O/D2O+ system are in excellent agreement with those for the OH/OH+ and H2O/H2O+ system after taking into account the zero-point vibration energies of these species.
