• Title of article

    Subpicosecond infrared spectroscopy on the photoisomerisation of the protonated Schiff base of all-trans retinal

  • Author/Authors

    Hamm، نويسنده , , P. and Zurek، نويسنده , , M. and Rِschinger، نويسنده , , T. and Patzelt، نويسنده , , H. and Oesterhelt، نويسنده , , D. and Zinth، نويسنده , , W.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1997
  • Pages
    7
  • From page
    180
  • To page
    186
  • Abstract
    The light induced isomerisation reaction of the protonated Schiff base retinal with butylamine was studied in solution by subpicosecond infrared spectroscopy in the spectral range of the CC, CC and CNH+ stretching modes. Upon heating by the internal S1 → S0 conversion process, vibrationally hot molecules are formed which are characterized by pronounced red-shifts of the CC, the CC and CNH+ stretching modes. The frequency shifts can be used to estimate an intramolecular temperature of the chromophore of 550 K immediately after the S1 → S0 transition.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1997
  • Journal title
    Chemical Physics Letters
  • Record number

    1780242

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1780242