Author/Authors :
S. and Soto-Bustamante، نويسنده , , E.A. and Werner، نويسنده , , R. and Weyrauch، نويسنده , , T. and Navarrete-Encina، نويسنده , , P.A. and Haase، نويسنده , , W.، نويسنده ,
Abstract :
To clarify the mechanism involved in the appearance of antiferroelectric properties in mixtures of polymers containing achiral mesogenic side chains and their monomers, X-ray investigation was carried out in pyroelectrically active samples. The thermal stability of such systems is also reported. The X-ray investigation shows that in highly concentrated mixtures of monomer in polymer, a segregation of the excess of monomer from an optimized ratio (33% monomer/polymer) occurs.