Detection of motion through susceptibility fields in two-dimensional exchange diffusive–MASS experiments

We show that the off-diagonal coherence peaks in two-dimensional Fourier transform NMR spectroscopy of fluids contained in porous media undergoing magic angle sample spinning (MASS) arise from amplitude modulation of the fluid’s magnetization. The amplitude modulation originates from the combined effect of MASS and the molecular diffusion through the inhomogeneous magnetic fields created by the susceptibility contrasts in the porous medium. The magnitude of the off-diagonal peaks provides information on the porous medium’s structural length scales, which give rise to correlation length scales of the magnetic susceptibility.