The third-order NLO properties of D-π-A molecules with changing a primary amino group into pyrrole

The nonlinear refractive index, as well as the two-photon absorption (TPA), has been investigated by the femtosecond Z-scan method for push–pull molecules, in which a primary donor group is weakened by conversion into a pyrrole or related heterocycle. The results at the fast response time show that, contrary to what had been expected from a previous work, there is a little decrease in the nonlinear refractive index change by introduction of the weaker donor groups. Although the measured TPA spectra showed that the observed nonlinear refractive index change was regarded to be off-resonant; difference in the frequency dispersion among the molecules considerably contributes to the decrease, in addition to difference in the intrinsic static nonlinearity. This shows that there is some future in the development of these non-resonant materials.