Title of article :
Selective excitation of the npσ1Σu+ and npπ1Πu to E,F 1Σg+ emission systems in molecular hydrogen using synchrotron radiation
Author/Authors :
ءlvarez Ruiz، نويسنده , , J and Erman، نويسنده , , P and Kivimنki، نويسنده , , A and Melero Garcia، نويسنده , , E and Rachlew، نويسنده , , E and Stankiewicz، نويسنده , , M، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Pages :
5
From page :
31
To page :
35
Abstract :
The npσ1Σu+ and npπ1Πu states in H2 have been selectively excited using monoenergetic synchrotron light in the range 14.4–15.5 eV and the subsequent emission was observed using a grating spectrometer. In total 22 well separated bands of the npσ1Σu+ and npπ1Πu to E,F 1Σg+ systems (n=3–7) were observed and rotationally analysed. The intensities of the P and R branches relative to the Q branch vary strongly in the npπ to EF bands confirming the existence of predissociations of a large number of npπ1Π+ levels. Energy levels of the E,F 1Σg+ state (vE,F=0, 1, 3, 6–10) are obtained which confirm earlier determinations from other H2 experiments.
Journal title :
Chemical Physics Letters
Serial Year :
2004
Journal title :
Chemical Physics Letters
Record number :
1783767
Link To Document :
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