Author/Authors :
To?ner، نويسنده , , Zden?k and Petrov، نويسنده , , Oleg and Dvinskikh، نويسنده , , Sergey V and Kowalewski، نويسنده , , Jozef and Sandstr?m، نويسنده , , Dick، نويسنده ,
Abstract :
In this Letter, we demonstrate the use of separated local-field NMR spectroscopy under magic-angle spinning conditions as a means of studying molecular reorientation in solid inclusion compounds. Site-resolved 1H–13C dipolar couplings were estimated in complexes between cryptophane-E and chloromethanes. We show that the mobilities of encaged guests in the solid state and of guests inside the host cavity in the isotropic liquid solution are very similar.
