• Title of article

    Hydrated-electron population dynamics

  • Author/Authors

    Pshenichnikov، نويسنده , , Maxim S. and Baltu?ka، نويسنده , , Andrius and Wiersma، نويسنده , , Douwe A. Wiersma، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    5
  • From page
    171
  • To page
    175
  • Abstract
    A detailed frequency-resolved pump–probe study of hydrated electron dynamics, performed with 5-fs pulses, is presented. We show that the experimental data can be successfully described with a model in which the excited state lifetime is ∼50 fs in regular water and ∼70 fs in heavy water. The deuteration effect on the lifetime strongly suggests that OH-vibrational modes in the first solvation shell act as accepting modes for energy relaxation.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2004
  • Journal title
    Chemical Physics Letters
  • Record number

    1784134