Author/Authors :
Duchamp، نويسنده , , James C. and Demortier، نويسنده , , Aline and Fletcher، نويسنده , , Kerra R. and Dorn، نويسنده , , Daniel and Iezzi، نويسنده , , Erick B. and Glass، نويسنده , , Tom and Dorn، نويسنده , , Harry C.، نويسنده ,
Abstract :
The discovery of a new isomer of the endohedral metallofullerene Sc3N@C80 is reported. 13C labeled (∼9%) Sc3N@C80 has been synthesized and has been characterized by HPLC, mass spectroscopy and 13C NMR data. The 13C NMR spectrum shows six peaks with a 1:2:2:1:1:1 ratio that are assigned to the D5h isomer. The results of theoretical calculations are also reported for the Ih and D5h isomers of Sc3N@C80.
