Author/Authors :
Ravikumar، نويسنده , , R.V.S.S.N. and Komatsu، نويسنده , , Ryuichi and Ikeda، نويسنده , , Ko. and Chandrasekhar، نويسنده , , A.V. Rami Reddy، نويسنده , , B.J. and Reddy، نويسنده , , Y.P. and Rao، نويسنده , , P.S.، نويسنده ,
Abstract :
EPR and optical absorption investigations of chromium doped cadmium phosphate glass are carried out. Crystal field, spin-Hamiltonian and bonding parameters are evaluated. From the results and analyses of the EPR and optical studies, the site symmetry of Cr3+ ion in the glass is ascribed to a distorted octahedron. The bonding parameters suggest the ionic nature of Cr3+ ion with the ligands.