Title of article
Thermodynamic optimization and calculation of the SmCl3–MCl (M=Na, K, Rb, Cs) phase diagrams
Author/Authors
Wang، نويسنده , , Yu and Sun، نويسنده , , Yimin and Qiao، نويسنده , , Zhiyu and Ye، نويسنده , , Xinyu and Ma، نويسنده , , Zhisen and Meng، نويسنده , , Xiangzhen، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
6
From page
317
To page
322
Abstract
The Gibbs energy of the liquid phases in the SmCl3–MCl (M=Na, K, Rb, Cs) systems is described by a modified quasi-chemical model. Based on measured phase equilibrium data and experimental thermochemical properties of these binary systems, a set of thermodynamic functions has been optimized by using the CALPHAD technique. The calculations based on the obtained descriptions show good agreement with experimental phase diagrams and thermodynamic values.
Keywords
Phase diagrams , Mixing enthalpy , SmCl3–MCl systems , Thermodynamic optimization and calculation
Journal title
Calphad
Serial Year
2005
Journal title
Calphad
Record number
1814709
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