Study of diffusion mobilities of Nb and Zr in bcc Nb–Zr alloys

On the basis of the available thermodynamic parameters, the atomic mobilities of Nb and Zr in bcc Nb–Zr alloys are critically assessed as functions of temperatures and compositions by the CALPHAD method, where self-diffusion coefficients, impurity diffusion coefficients, tracer diffusion coefficients, interdiffusion coefficients and concentration curves are simultaneously optimized. Comparisons between the calculated and experimentally measured diffusion coefficients are made, where good agreement is evident. In addition, the obtained mobility parameters can reproduce a reasonable concentration profile for the Nb/Zr diffusion couple annealed at 1868 K for 5400 s.