Title of article
Thermodynamic assessment of TbCl3–MCl (M=Na, K, Rb, Cs) binary systems
Author/Authors
Kapa?a، نويسنده , , Jan and Salamon، نويسنده , , Beata، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
139
To page
142
Abstract
The phase diagrams of TbCl3–MCl (M=Na, K, Rb, Cs) binary systems were reassessed by CALPHAD method. The liquid phase has been described by the associate model with main 3Na++TbCl63− associate. The Gibbs energies of formation of solid compounds were calculated and compared with previous data. The entropy of mixing of the liquid phase has been used for the interpretation of structure of this phase.
Keywords
Gibbs energy of formation , Associate model , Alkali metal chloride , phase diagram , Entropy of mixing , Terbium chloride
Journal title
Calphad
Serial Year
2013
Journal title
Calphad
Record number
1816487
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