Title of article
Stable axial-rich chair conformer of myo-inositol derivatives due to introduction of two adjacent bulky silyl protections
Author/Authors
Yamada، نويسنده , , Hidetoshi and Okajima، نويسنده , , Kotaro and Imagawa، نويسنده , , Hiroshi and Mukae، نويسنده , , Tatsuya and Kawamura، نويسنده , , Yoshiaki and Nishizawa، نويسنده , , Mugio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
3157
To page
3160
Abstract
The ring-conformational change of myo-inositol derivatives by introducing two tert-butyldimethylsilyl, triisopropylsilyl, or tert-butyldiphenylsilyl groups into the 1,2-trans hydroxy groups––3,4- and 4,5-positions––were investigated. The cyclohexane cores of the 4,5-bis-O-silylated derivatives with tert-butyldiphenylsilyl or triisopropylsilyl groups were present in the axial-rich chair form.
Keywords
Silyl protecting groups , ring conformation , Axial-rich chair , Myo-inositol
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841296
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