Author/Authors :
Uddin، نويسنده , , Md.Khabir and Fujiyama، نويسنده , , Ryoji and Kiyooka، نويسنده , , Syun-ichi and Fujio، نويسنده , , Mizue and Tsuno، نويسنده , , Yuho، نويسنده ,
Abstract :
The electrophilic abstraction of chloride ion by SbCl5 from diphenylchloroborane in CD3NO2 resulted in a transient species of which 11B NMR chemical shift appeared at 20 ppm. This was indicative of diphenylboron cation, stabilized with electron donor O-atom of two nitromethane molecules. The experimental 11B chemical shift for the solvated diphenylboron cation is in good agreement with that calculated by GIAO-HF/6-311+G(2d,p)//B3LYP/6-31+G(d).
