Author/Authors :
Takatani، نويسنده , , Maki and Nakano، نويسنده , , Jun and Arai، نويسنده , , Midori A. and Ishiwata، نويسنده , , Akihiro and Ohta، نويسنده , , Hiromichi and Ito، نويسنده , , Yukishige، نويسنده ,
Abstract :
O-Glycosylations using thiomethyl glycosides as donors were compared under both frozen and unfrozen conditions. In the presence of MeOTf as a promoter, enormous rate acceleration was observed when the glycosylation was conducted in p-xylene below its freezing point.
Keywords :
High-mannose type , Oligosaccharide , glycosylation , Frozen , Rate acceleration
