Title of article
Towards the total synthesis of tonantzitlolone––preparation of key fragments and the complete carbon backbone
Author/Authors
Wittenberg، نويسنده , , Rüdiger and Beier، نويسنده , , Christian and Drنger، نويسنده , , Gerald and Jas، نويسنده , , Gerhard and Jasper، نويسنده , , Christian and Monenschein، نويسنده , , Holger and Kirschning، نويسنده , , Andreas، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
4457
To page
4460
Abstract
The first synthetic advances towards the novel diterpenoid tonantzitlolone 1 are described. The key steps in the synthesis involve a chromium(II) Reformatsky reaction, a diastereoselective C1 extension and an expeditious aldol coupling step of two advanced precursors.
Keywords
terpene , Chromium Reformatsky reaction , polymer-supported reagents , total synthesis , Formylation
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841892
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