Title of article
Promotion of one-pot Robinson annelation achieved by gradual pressure and temperature manipulation under supercritical conditions
Author/Authors
Kawanami، نويسنده , , Hajime and Ikushima، نويسنده , , Yutaka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
5147
To page
5150
Abstract
The one-pot Robinson annelation from 2-methyl-cyclohexane-1,3-dione with 3-buten-2-one can be achieved in high yield (95%) and high selectivity (95%) by pressure and temperature manipulation using supercritical carbon dioxide in the presence of MgO catalyst, whose method could be applied for various ketones to synthesize fused polycyclic compounds.
Keywords
one-pot reaction , supercritical CO2 , Robinson annelation
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842257
Link To Document