Title of article
Dye-sensitized intrazeolite photooxygenation of 4-substituted cyclohexenes. Remote substituent effects in regioselectivity and diastereoselectivity
Author/Authors
Stratakis، نويسنده , , Manolis and Sofikiti، نويسنده , , Nikoletta and Baskakis، نويسنده , , Constantinos and Raptis، نويسنده , , Christos، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
5433
To page
5436
Abstract
The product distribution in the dye-sensitized photooxygenation of α-terpinyl acetate and terpinen-4-ol is quite similar in solution, however, by zeolite Y confinement, is substantially influenced by the position of the remote polar substituents relative to the reacting double bond. The intrazeolite results were rationalized in terms of Na+-substrate and Na+-singlet oxygen interactions.
Keywords
diastereoselection , Zeolite NaY , Terpenes , singlet oxygen , Hydroperoxides
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842398
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