Title of article
Development of bis-thiourea-type organocatalyst for asymmetric Baylis–Hillman reaction
Author/Authors
Sohtome، نويسنده , , Yoshihiro and Tanatani، نويسنده , , Aya and Hashimoto، نويسنده , , Yuichi and Nagasawa، نويسنده , , Kazuo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
5589
To page
5592
Abstract
A new chiral bis-thiourea-type organocatalyst 2 developed for the Baylis–Hillman reaction provided a drastic rate enhancement. Allylic alcohols were obtained with up to 90% ee in the case of cyclohexanecarboxaldehyde (4i).
Keywords
Baylis–Hillman reaction , organocatalyst , Asymmetric reaction , Bis-thiourea
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842512
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