Title of article
Dendritic phosphoramidite ligands in Rh-catalysed asymmetric hydrogenations
Author/Authors
Botman، نويسنده , , Peter N.M and Amore، نويسنده , , Alessia and van Heerbeek، نويسنده , , Rieko and Willem Back، نويسنده , , Jaap and Hiemstra، نويسنده , , Henk and Reek، نويسنده , , Joost N.H and van Maarseveen، نويسنده , , Jan H، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
5999
To page
6002
Abstract
The axially chiral BICOL backbone was functionalised with two third generation carbosilane dendritic wedges and further elaborated to a phosphoramidite ligand. High enantioselectivities were obtained when these monodentate ligands were applied in the rhodium-catalysed asymmetric hydrogenation of methyl 2-acetamidocinnamate.
Keywords
Dendrimers , Homogeneous catalysis , Asymmetric hydrogenations , Phosphoramidite ligands
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842838
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