Title of article
Novel features of iron-mediated radical reactions: an unusual mode of silyloxycyclopropane fission, and a new method for radical chain termination using CH2I2
Author/Authors
John Highton، نويسنده , , Adrian and Volpicelli، نويسنده , , Raffaella and Simpkins، نويسنده , , Nigel S.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
6679
To page
6683
Abstract
Fe(NO3)3 mediated radical reactions of silyloxycyclopropanes derived from a range of bicyclic ketones are described, and include examples that undergo an unexpected regiochemical mode of cyclopropane cleavage. The inclusion of CH2I2 in such reactions allows the synthesis of iodinated products.
Keywords
Cyclopropane , iodination , Radical cyclisation , Iron salts
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843119
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